Interlaminar and ductile characteristics of carbon fibers-reinforced plastics produced by nanoscaled electroless nickel plating on carbon fiber surfaces.

Interlaminar and ductile characteristics of carbon fibers-reinforced plastics produced by nanoscaled electroless nickel plating on carbon fiber surfaces.
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DOI:
10.1006/jcis.2001.8040
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发表时间:
2002-01
影响因子:
9.9
通讯作者:
Soojin Park;Yu-Sin Jang;K. Rhee
Soojin Park;Yu-Sin Jang;K. Rhee
中科院分区:
化学1区
文献类型:
--
作者:
Soojin Park;Yu-Sin Jang;K. Rhee

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在这项工作中,提出了一种基于碳纤维表面纳米级Ni-P合金涂层的新方法,用于改善复合材料系统中纤维与环氧树脂基体之间的界面性能。通过原子吸收分光光度计(AAS)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、层间剪切强度(ILSS)和冲击强度表征复合材料的纤维表面和机械界面性能。实验结果表明,随着化学镀镍的进行,O(1s)/C(1s)比值或Ni、P含量增加; ILSS 也略有改善。碳纤维表面存在Ni-P合金时,冲击性能显着改善,增加了复合材料的延展性。这可能是由于取代的Ni-P合金的作用,导致环氧树脂体系的抗变形和裂纹萌生能力增加。
In this work, a new method based on nanoscaled Ni-P alloy coating on carbon fiber surfaces is proposed for the improvement of interfacial properties between fibers and epoxy matrix in a composite system. Fiber surfaces and the mechanical interfacial properties of composites were characterized by atomic absorption spectrophotometer (AAS), scanning electron microscopy (SEM), X-ray photoelectron spectrometry (XPS), interlaminar shear strength (ILSS), and impact strength. Experimental results showed that the O(1s)/C(1s) ratio or Ni and P amounts had been increased as the electroless nickel plating proceeded; the ILSS had also been slightly improved. The impact properties were significantly improved in the presence of Ni-P alloy on carbon fiber surfaces, increasing the ductility of the composites. This was probably due to the effect of substituted Ni-P alloy, leading to an increase of the resistance to the deformation and the crack initiation of the epoxy system.