Gated electron-transfer behavior in copper(II/I) systems. Comparison of the kinetics for homogeneous cross reactions, NMR self-exchange relaxation, and electrochemical data for a copper macrocyclic tetrathioether complex in aqueous solution

Gated electron-transfer behavior in copper(II/I) systems. Comparison of the kinetics for homogeneous cross reactions, NMR self-exchange relaxation, and electrochemical data for a copper macrocyclic tetrathioether complex in aqueous solution
复制标题

铜(II/I)系统中的门控电子转移行为。

DOI:
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发表时间:
1992
期刊:
影响因子:
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通讯作者:
D. Rorabacher
D. Rorabacher
中科院分区:
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文献类型:
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作者:
N. E. Meagher;Kerri L. Juntunen;Cynthia A. Salhi;L. Ochrymowycz;D. Rorabacher

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在水溶液中,测定了Cu Ⅱ/I([14]aneS 4)与一系列抗衡试剂的电子转移反应动力学,反应温度为25 ℃,r= 0.10M(ClO 4 -)。
The kinetics of electron-transfer reactions involving Cu II/I ([14]aneS 4 ) reacting with a series of selected counterreagents have been measured in aqueous solution at 25 o C, r=0.10 M (ClO 4 - ).