CONCENTRATION WAVE PROPAGATION IN 2-DIMENSIONAL LIQUID-PHASE SELF-OSCILLATING SYSTEM
CONCENTRATION WAVE PROPAGATION IN 2-DIMENSIONAL LIQUID-PHASE SELF-OSCILLATING SYSTEM
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DOI：
10.1038/225535b0
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发表时间：
1970-01-01
期刊：
影响因子：
64.8
通讯作者：
ZHABOTINSKY, AM
中科院分区：
文献类型：
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作者：
ZAIKIN, AN;ZHABOTINSKY, AM
振荡化学反应不仅本身很有趣，而且作为许多重要生物过程的模型也很有趣。在振荡反应中，铈（或锰）离子催化溴酸6 - 8氧化丙二酸类似物。氧化和还原形式的催化剂浓度的振荡引起溶液颜色的振荡，而搅拌导致整个体积的振荡强制同步。在没有搅拌的情况下，浓度波在一定条件下会周期性传播，这种现象在一维系统（长管）中已经描述过9,10。我们的工作涉及解决方案（二维系统）的薄层模式。
OSCILLATING chemical reactions are interesting, not only in themselves but as models of a number of important biological processes1–5. Oscillating reactions have been described in which cerium (or manganese) ions catalyse the oxidation of analogues of malonic acid by bromate6–8. Oscillations in the concentrations of oxidized and reduced forms of the catalyst cause oscillations in the solution colour, while stirring leads to forced synchronization of oscillations throughout the whole volume. In the absence of stirring, periodic propagation of concentration waves occurs in certain conditions, and such a phenomenon in a one-dimensional system (a long tube) has been described9,10. Our work deals with patterns in a thin layer of solution (two-dimensional system).