Keggin unit supported transition metal complexes: hydrothermal synthesis and characterization of [Ni(2,2′-bipy)3]1.5[PW12O40Ni(2,2′-bipy)2(H2O)]·0.5H2O and [Co(1,10′-phen)3]1.5[PMo12O40Co(1,10′-phen)2(H2O)]·0.5H2O
Keggin unit supported transition metal complexes: hydrothermal synthesis and characterization of [Ni(2,2′-bipy)3]1.5[PW12O40Ni(2,2′-bipy)2(H2O)]·0.5H2O and [Co(1,10′-phen)3]1.5[PMo12O40Co(1,10′-phen)2(H2O)]·0.5H2O
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DOI：
10.1039/a908527k
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发表时间：
2000
影响因子：
4.9
通讯作者：
Yan Xu;Ji-qing Xu;Kou-Lin Zhang;Yong Zhang;X. You
中科院分区：
文献类型：
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作者：
Yan Xu;Ji-qing Xu;Kou-Lin Zhang;Yong Zhang;X. You
采用水热法合成了两个新的Keggin单元负载的过渡金属配合物[Ni(2,2 ' -bipy)3]1.5[PW12O40Ni(2,2 ' -bipy)2(H2O)]·0.5H2O 1和[Co(1,10 ' -phen)3]1.5[PMo12O40Co(1,10 ',-phen)2- (H2O)]·0.5H2O 2；x射线晶体学表征了配合物1，表明[Ni(2,2 ' -bipy)2(H2O)]2+单元与α-Keggin簇[PWV2- WVI10O40]共价键合5。
Two new Keggin unit supported transition metal complexes, [Ni(2,2′-bipy)3]1.5[PW12O40Ni(2,2′-bipy)2(H2O)]·0.5H2O 1 and [Co(1,10′-phen)3]1.5[PMo12O40Co(1,10′,-phen)2- (H2O)]·0.5H2O 2, are synthesized by a hydrothermal method; complex 1 is characterized by X-ray crystallography, showing that the [Ni(2,2′-bipy)2(H2O)]2+ units are covalently bonded to the α-Keggin cluster [PWV2- WVI10O40]5.