An efficient synthesis of novel fused cycloheptatrienes through Mn(II)-mediated formal intermolecular [2 + 2 + 2 + 1] cycloaddition.
An efficient synthesis of novel fused cycloheptatrienes through Mn(II)-mediated formal intermolecular [2 + 2 + 2 + 1] cycloaddition.
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DOI：
10.1021/ol500202q
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发表时间：
2014-02
期刊：
影响因子：
5.2
通讯作者：
Wen-Ming Shu;Junrui Ma;Yan Yang;A. Wu
中科院分区：
文献类型：
--
作者：
Wen-Ming Shu;Junrui Ma;Yan Yang;A. Wu
A new method for manganous acetate tetrahydrate mediated formal intermolecular [2 + 2 + 2 + 1] cycloaddition was developed for the synthesis of fused cycloheptatriene derivatives from N-(acylmethyl)pyridinium iodides and naphthoquinone. This method provides an innovative route for the efficient and convenient construction of fused seven-membered carbocycles from simple starting materials.
