Reaction in supercritical CO2;: an intercalation of 4-phenylazoaniline between layers of montmorillonite pillared with tetramethylammonium ions
Reaction in supercritical CO2;: an intercalation of 4-phenylazoaniline between layers of montmorillonite pillared with tetramethylammonium ions
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DOI：
10.1039/a803540g
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发表时间：
1998-08-21
影响因子：
4.9
通讯作者：
Ooi, K
中科院分区：
文献类型：
--
作者：
Ishii, R;Wada, H;Ooi, K
在T=313K(P=15 Mpa)的超临界CO_2(SCC)中，4-苯基偶氮苯胺插层到四甲基铵离子柱撑蒙脱土中的反应获得了成功，表明SCC是一种比有机溶液更好的介质，可以在不污染溶剂的情况下将大量客体分子插层到主体化合物中。
The intercalation reaction of 4-phenylazoaniline into montmorillonite pillared with tetramethylammonium ions has been performed successfully in supercritical CO2 (SCC) at T = 313 K (P = 15 MPa), demonstrating that SCC is a better medium than organic solutions for intercalating large amounts of guest molecules into a host compound without the contamination of solvent.