One-pot synthesis of benzo[1,4]thiazin-3(4H)-ones and a Theoretical Study of the S-N type Smiles rearrangement mechanism.
One-pot synthesis of benzo[1,4]thiazin-3(4H)-ones and a Theoretical Study of the S-N type Smiles rearrangement mechanism.
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DOI：
10.1021/jo3014287
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发表时间：
2012-09
期刊：
影响因子：
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通讯作者：
Yongmei Zhao;Yanmiao Wu;Jiong Jia;Dongju Zhang;Chen Ma
中科院分区：
文献类型：
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作者：
Yongmei Zhao;Yanmiao Wu;Jiong Jia;Dongju Zhang;Chen Ma
苯并[1，4]噻嗪-3（4 H）-酮衍生物通过Smiles重排（SR）串联反应方便地在一锅中制备。为了更好地理解这一反应，本文对S-N型SR机理进行了理论研究。
Benzo[1,4]thiazin-3(4H)-one derivatives are conveniently prepared in one pot via a Smiles rearrangement (SR) tandem reaction. In order to understand the reaction, we present here a theoretical study on the S-N type SR mechanism.