Hydrogen Storage in Metal-Organic Frameworks
Hydrogen Storage in Metal-Organic Frameworks
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DOI：
10.1007/978-3-662-53514-1_5
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
L. Zou;Hong-Cai Zhou
中科院分区：
文献类型：
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作者：
L. Zou;Hong-Cai Zhou
在过去的二十年里，金属-有机骨架（MOFs），由有机连接体和无机金属簇之间的配位键构建而成，由于其异常的高孔隙率、高结晶度、均匀但可调节的孔径和孔形状、巨大的结构多样性以及各种氢占据位点，已经成为一个新兴的研究领域和一个巨大的潜在的储氢候选者。在这里，一些技术要素，包括句法，合成，制造，评估和基准测试，在剪裁MOFs作为储氢树脂介绍。作为实例，在储氢的上下文中讨论了由羧酸酯、唑酸酯或混合接头构建的M0 F。最后但并非最不重要的是，MOF材料的合成后修饰，以增加储氢容量将被仔细说明。
In the past two decades, metal-organic frameworks (MOFs), constructed with coordination bonds between organic linkers and inorganic metal clusters, have become a burgeoning field of research and a great potential candidate for hydrogen storage due to their exceptional high porosity, high crystallinity, uniform yet tunable pore size and pore shape, great structural diversity, and various kinds of hydrogen occupation sites. Here, some technical elements are introduced in tailoring MOFs as hydrogen storage resins, including syntax, synthesis, fabrication, evaluation, and benchmark testing. As way of example, MOFs constructed by carboxylate, azolate or mixed linkers, are discussed in the context of hydrogen storage. Last but not least, the postsynthetic modifications on MOF materials to increase the hydrogen storage capacities will be carefully illustrated.