Synthesis and Properties of Single-Walled Carbon Nanotubes Filled with Metal Halogenides and Metallocenes
Synthesis and Properties of Single-Walled Carbon Nanotubes Filled with Metal Halogenides and Metallocenes
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DOI：
10.5772/intechopen.85062
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发表时间：
2019-03
期刊：
影响因子：
--
通讯作者：
M. Kharlamova;D. Eder
中科院分区：
文献类型：
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作者：
M. Kharlamova;D. Eder
本章综述了金属卤化物和茂金属填充单壁碳纳米管（SWCNT）的电子性能以及茂金属填充纳米管内部单壁碳纳米管的生长动力学的研究现状。本章首先描述了金属卤化物填充单壁碳纳米管的合成特点，比较了不同填充方法及其优点、缺点和限制。然后，我们全面总结、比较和批判性讨论了金属卤化物填充单壁碳纳米管电子性能的最新研究。之后，描述了茂金属填充的单壁碳纳米管的合成方法，并总结了填充纳米管内内部单壁碳纳米管生长动力学的研究结果。然后，回顾了专门研究茂金属填充的单壁碳纳米管电子性能的报告。最后，强调了填充型单壁碳纳米管未来研究、开发和应用的潜力。 SWCNT 填充后的数量。 OAS 提供有关纳米管结构相关光学跃迁的信息。拉曼光谱可以研究单壁碳纳米管的振动特性。 XPS 研究填充的单壁碳纳米管中的费米能级位移和键合环境。
This chapter reviews the current status of the research on the electronic properties of single-walled carbon nanotubes (SWCNTs) filled with metal halogenides and metallocenes and growth kinetics of inner SWCNTs inside metallocene-filled nanotubes. The chapter starts with the description of the peculiarities of the synthesis of metal halogenide-filled SWCNTs, comparison of different filling methods, their advantages, disadvantages, and restrictions. Then, we comprehensively summarize, compare, and critically discuss the recent studies on the electronic properties of metal halogenide-filled SWCNTs. After that, the synthesis methods of metallocene-filled SWCNTs are described and the results of the investigation of the growth kinetics of inner SWCNTs inside the filled nanotubes are summarized. Then, the reports dedicated to the investigation of the electronic properties of metallocene-filled SWCNTs are reviewed. Finally, potentials for future research, development, and application of filled SWCNTs are highlighted. of SWCNTs upon their filling. OAS gives information about structure-dependent optical transitions of nanotubes. Raman spectroscopy allows studying the vibronic properties of SWCNTs. XPS investigates the Fermi level shift and bonding environment in filled SWCNTs.