Nucleophilic substitution of (alkoxymethylene)dimethylammonium chloride with carboxylate salts: a convenient procedure for the synthesis of esters with inversion of configuration

Nucleophilic substitution of (alkoxymethylene)dimethylammonium chloride with carboxylate salts: a convenient procedure for the synthesis of esters with inversion of configuration
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(烷氧基亚甲基)二甲基氯化铵与羧酸盐的亲核取代:构型反转合成酯的简便方法

DOI:
10.1039/c39950001403
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发表时间:
1995
期刊:
Journal of The Chemical Society, Chemical Communications
影响因子:
--
通讯作者:
P. Procopiou
P. Procopiou
中科院分区:
--
文献类型:
--
作者:
A. Barrett;N. Koike;P. Procopiou

文献摘要

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仲醇通过与(氯亚甲基)二甲基氯化铵和苯甲酸钾的顺序反应转化为苯甲酸酯,并转化为构型。
Secondary alcohols are converted into benzoate esters with inversion of configuration via sequential reaction with (chloromethylene)dimethylammonium chloride and potassium benzoate.