Antagonism in the extraction of uranium(VI) by the binary mixture of PC88A and benzimidazole

Antagonism in the extraction of uranium(VI) by the binary mixture of PC88A and benzimidazole
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PC88A与苯并咪唑二元混合物萃取铀(VI)的拮抗作用

DOI:
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发表时间:
1999
期刊:
影响因子:
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通讯作者:
V. Chakravortty
V. Chakravortty
中科院分区:
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文献类型:
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作者:
A. Mukherjee;S. Kamila;V. Chakravortty

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用PC 88 A和苯并咪唑的二元混合物萃取铀(VI)的研究表明,在10−5-10− 6 M的PC 88 A和0.005 M的苯并咪唑浓度范围内,存在拮抗行为。由于苯并咪唑使PC 88 A去质子化形成加合物,导致从系统中实际除去PC 88 A,因此观察到拮抗作用。
Extraction studies of uranium(VI) by the binary mixture of PC88A and benzimidazole show an antagonistic behavior in the concentration range 10−5–10−6M of PC88A and 0.005M of benzimidazole. Antagonism is observed due to the deprotonation of PC88A by benzimidazole forming an adduct resulting in the virtual removal of PC88A from the system.