Self-assembly of octarhenium-based neutral luminescent rectangular prisms
Self-assembly of octarhenium-based neutral luminescent rectangular prisms
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DOI：
10.1021/ic034172j
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发表时间：
2003-08-11
影响因子：
4.6
通讯作者：
Lu, KL
中科院分区：
文献类型：
--
作者：
Manimaran, B;Thanasekaran, P;Lu, KL
在定量转换中实现了铱基纳米尺度矩形棱柱盒的自组装。工厂的角落提供了三个相互垂直的协调点，是一个很好的候选人，为建设三维框。这是第一个稀土基的，中性的，发光棱镜的M8L2L '（8）型，已被晶体学的特点。它们的发光性质和分子识别能力使这些分子棱柱成为有趣的超分子。
Self-assembly of rhenium-based nanoscale rectangular prismatic boxes has been achieved in quantitative conversion. The facrhenium corner provided three mutually perpendicular coordination sites and served as a good candidate for the construction of 3-D boxes. These are the first Re-based, neutral, luminescent prisms of M8L2L'(8) type that has been characterized crystallographically. Their luminescent properties and molecular recognition capabilities make these molecular prisms interesting supramolecules.