Total synthesis of methyl sarcophytoate
Total synthesis of methyl sarcophytoate
复制标题
DOI：
10.1021/ja073952e
复制
发表时间：
2007-08-15
影响因子：
15
通讯作者：
Nakata, Masaya
中科院分区：
文献类型：
--
作者：
Ichige, Takahiro;Okano, Yusuke;Nakata, Masaya
与双膜类海洋天然产物-肌酸甲酯(1)的二烯单元15的改进合成一起，通过二烯单元、肌酸甲酯(2)和15之间的热Diels-Alder反应实现了1的不对称全合成。
Together with the improved synthesis of the diene unit 15 of methyl sarcophytoate (1), a biscembranoid marine natural product, the asymmetric total synthesis of 1 was achieved by the thermal Diels-Alder reaction between the dienophile unit, methyl sarcoate (2), and 15.