Self-propagating high-temperature synthesis of Ce-bearing zirconolite-rich minerals using Ca(NO3)2 as the oxidant
Self-propagating high-temperature synthesis of Ce-bearing zirconolite-rich minerals using Ca(NO3)2 as the oxidant
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以Ca(NO3)2为氧化剂自蔓延高温合成富Ce锆石矿物
DOI：
10.1016/j.jnucmat.2015.09.042
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发表时间：
2015-12
影响因子：
3.1
通讯作者：
Yuxiang Li
中科院分区：
文献类型：
--
作者：
Guanjun Wen;Haibin Zhang;Yuancheng Teng;Yuxiang Li
Synroc is recognized as the second generation waste form for the immobilization of high-level radioactive waste (HLW). Zirconolite-rich (CaZrTi2O7) Synroc minerals were attempted by self-propagating high-temperature synthesis (SHS) using Fe2O3, CrO3, Ca(NO3)2as the oxidants and Ti as the reductant. All designed reactions were ignited and sustained using Ca(NO3)2as the oxidant, and zirconolite-rich ceramic matrices were successfully prepared with pyrochlore (Ca2Ti2O6), perovskite (CaTiO3) and rutile (TiO2) as the minor phases. The sample CN-4, which was designed using Ca(NO3)2as the oxidant with TiO2/Ti ratio of 7:9, was readily solidified with density of 4.62 g/cm3and Vickers hardness of 1052 HV. CeO2was successfully stabilized by the CN-4 sample with resultant phase constituent of 2M-CaZrTi2O7and CaTiO3.
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影响因子：
3.1
作者：
Caurant, D.;Majerus, O.;Dussossoy, J. L.
通讯作者：
Dussossoy, J. L.
影响因子：
4.5
作者：
Pascal Loiseau;D. Caurant;O. Majérus;N. Baffier;C. Fillet
通讯作者：
Pascal Loiseau;D. Caurant;O. Majérus;N. Baffier;C. Fillet
DOI：
10.1557/proc-932-61.1
发表时间：
2006
期刊：
MRS Proceedings
影响因子：
--
作者：
P. McGlinn;T. Advocat;G. Leturcq;T. McLeod;Z. Aly;P. Yee
通讯作者：
P. McGlinn;T. Advocat;G. Leturcq;T. McLeod;Z. Aly;P. Yee
DOI：
10.1016/s0168-583x(98)00847-7
发表时间：
1999-01
影响因子：
1.3
作者：
S. X. Wang;Luming Wang;R. Ewing;G. Was;G. Lumpkin
通讯作者：
S. X. Wang;Luming Wang;R. Ewing;G. Was;G. Lumpkin
影响因子：
0.9
作者：
T. Barinova;I. Borovinskaya;V. I. Ratnikov;T. Ignat’eva
通讯作者：
T. Barinova;I. Borovinskaya;V. I. Ratnikov;T. Ignat’eva