Selective photocatalytic oxidation of aromatic alcohols to aldehydes in an aqueous suspension of gold nanoparticles supported on cerium(IV) oxide under irradiation of green light.

Selective photocatalytic oxidation of aromatic alcohols to aldehydes in an aqueous suspension of gold nanoparticles supported on cerium(IV) oxide under irradiation of green light.
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DOI:
10.1039/c1cc13801d
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发表时间:
2011-09
影响因子:
4.9
通讯作者:
A. Tanaka;K. Hashimoto;H. Kominami
A. Tanaka;K. Hashimoto;H. Kominami
中科院分区:
化学2区
文献类型:
--
作者:
A. Tanaka;K. Hashimoto;H. Kominami

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负载在氧化铈(IV)粉末上的金纳米粒子由于表面等离子体共振在约550 nm处有强吸收,在绿光照射下,其在水悬浮液中可几乎定量地将芳香醇氧化为相应的醛。
Gold nanoparticles supported on cerium(IV) oxide powder showing strong absorption at around 550 nm due to surface plasmon resonance oxidized aromatic alcohols to corresponding aldehydes almost quantitatively in an aqueous suspension under irradiation of green light.