Hydrogen Storage Materials for Mobile and Stationary Applications: Current State of the Art

Hydrogen Storage Materials for Mobile and Stationary Applications: Current State of the Art
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DOI:
10.1002/cssc.201500231
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发表时间:
2015-09-01
期刊:
影响因子:
8.4
通讯作者:
Aguey-Zinsou, Kondo-Francois
Aguey-Zinsou, Kondo-Francois
中科院分区:
化学2区
文献类型:
--
作者:
Lai, Qiwen;Paskevicius, Mark;Aguey-Zinsou, Kondo-Francois

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氢作为一种能量载体的广泛使用的限制之一是它的储存在一个安全和紧凑的形式。本文综述了高效高容量储氢材料的最新进展,特别强调了轻化合物,包括基于有机多孔结构、硼、氮和铝的化合物。这些元素及其相关化合物有望为移动应用提供高、可逆和实用的储氢能力,包括车辆和便携式电源设备,也可用于固定应用的大规模和分布式能量存储。总结了目前对氢与这些轻化合物相互作用的基本原理的理解,以及实现氢吸收和释放的基本策略。讨论了这些策略的局限性和目前的认识,并提出了新的方向。
One of the limitations to the widespread use of hydrogen as an energy carrier is its storage in a safe and compact form. Herein, recent developments in effective high-capacity hydrogen storage materials are reviewed, with a special emphasis on light compounds, including those based on organic porous structures, boron, nitrogen, and aluminum. These elements and their related compounds hold the promise of high, reversible, and practical hydrogen storage capacity for mobile applications, including vehicles and portable power equipment, but also for the large scale and distributed storage of energy for stationary applications. Current understanding of the fundamental principles that govern the interaction of hydrogen with these light compounds is summarized, as well as basic strategies to meet practical targets of hydrogen uptake and release. The limitation of these strategies and current understanding is also discussed and new directions proposed.