Remote Oxygen Migration Reaction between Sulfur Atoms in 1,4-Bis(methylthio)benzene Derivatives: Possible Formation of Bis(dithia dication) Dimer as an Intermediate
Remote Oxygen Migration Reaction between Sulfur Atoms in 1,4-Bis(methylthio)benzene Derivatives: Possible Formation of Bis(dithia dication) Dimer as an Intermediate
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1,4-双（甲硫基）苯衍生物中硫原子之间的远程氧迁移反应：可能形成双（二硫基阳离子）二聚体作为中间体
DOI：
10.1246/cl.1997.1175
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发表时间：
1997
影响因子：
1.6
通讯作者：
N. Furukawa
中科院分区：
文献类型：
--
作者：
Kenji Kobayashi;Takanobu Obinata;N. Furukawa
1,4-双(甲硫基)苯一氧化物中硫原子之间的氧迁移反应在 CF3CO2H 存在下进行。 1,4-双(甲硫基)苯与其双亚砜在室温下反应也得到相应的一氧化物。提议将两点双（二硫基双氧）二聚体作为中间体。
The oxygen migration reaction between sulfur atoms in the monooxide of 1,4-bis(methylthio)benzene preceeds in the presence of CF3CO2H. The reaction of 1,4-bis(methylthio)benzene with its bis-sulfoxide also gives the corresponding monooxide at room temperature. A two-point bis(dithia dication) dimer is proposed as an intermediate.