Room temperature hydrogenation of furfuryl alcohol by Pd/titanate nanotube
Room temperature hydrogenation of furfuryl alcohol by Pd/titanate nanotube
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DOI：
10.1016/j.apcata.2015.09.034
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发表时间：
2015-10
影响因子：
5.5
通讯作者：
Qingqing Yuan;Feiyang Ye;Teng Xue;Y. Guan
中科院分区：
文献类型：
--
作者：
Qingqing Yuan;Feiyang Ye;Teng Xue;Y. Guan
The liquid phase hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol at room temperature under 1 atm hydrogen was succeeded on a TiO2nanotube (TNT) supported palladium catalyst. The palladium nanoparticles in size of 2–8 nm were loaded by the deposition-reduction method with NaBH4as reducing reagent. The Pd/TNT catalyst showed high dispersion as revealed by CO chemisorption and improved catalytic performance in terms of both furfuryl alcohol conversion and tetrahydrofurfuryl alcohol selectivity, probably attributed to the unique electronic interaction between Pd metals and TNT surface containing sodium cations. Among the catalysts investigated, 5.8 wt.% Pd/TNT showed the best performance, with 98% conversion and 98% selectivity to tetrahydrofurfuryl alcohol in ethanol.
