Arene-Free Ruthenium(II/IV)-Catalyzed Bifurcated Arylation for Oxidative C-H/C-H Functionalizations.
Arene-Free Ruthenium(II/IV)-Catalyzed Bifurcated Arylation for Oxidative C-H/C-H Functionalizations.
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DOI：
10.1002/anie.201909457
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发表时间：
2019-10
影响因子：
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通讯作者：
T. Rogge;L. Ackermann
中科院分区：
文献类型：
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作者：
T. Rogge;L. Ackermann
实验和计算研究提供了详细的洞察选择性和反应性控制因素在分叉的铼催化的直接C-H芳基化和双C-H/C-H官能化。彻底的调查揭示了芳烃配体的配合物的重要性，形成双环内钌（II/IV/II）的机械流形的中间体。
Experimental and computational studies provided detailed insights into selectivity- and reactivity-controlling factors in bifurcated ruthenium-catalyzed direct C-H arylations and dehydrogenative C-H/C-H functionalizations. Thorough investigations revealed the importance of arene-ligand-free complexes for the formation of biscyclometalated intermediates within a ruthenium(II/IV/II) mechanistic manifold.