Carbene-Stabilized Main Group Radicals and Radical Ions.
Carbene-Stabilized Main Group Radicals and Radical Ions.
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DOI：
10.1039/c3sc51174j
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发表时间：
2013-08-01
期刊：
影响因子：
8.4
通讯作者：
Bertrand G
中科院分区：
文献类型：
--
作者：
Martin CD;Soleilhavoup M;Bertrand G
稳定的单重态卡宾在80年代末被发现后不久就被认为是过渡金属基催化剂的优良配体，并且本身也是有机催化剂。在2000年代末，已经表明它们可以在零氧化态下与主族元素配位，甚至活化小分子。本文综述了文献中稳定单态卡宾的最新应用，即它们用于稳定自由基和自由基离子，否则不稳定的例子。
Shortly after their discovery at the end of the 80s, stable singlet carbenes have been recognized as excellent ligands for transition metal based catalysts, and as organo-catalysts in their own right. At the end of the 2000s, it has been shown that they can coordinate main group elements in their zero oxidation state, and even activate small molecules. This review covers examples in the literature dealing with the most recent application of stable singlet carbenes, namely their use to stabilize radicals and radical ions that are otherwise unstable.