Experimental investigation of anion-π interactions - applications and biochemical relevance
Experimental investigation of anion-π interactions - applications and biochemical relevance
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DOI：
10.1039/c5cc09072e
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发表时间：
2016-01-01
影响因子：
4.9
通讯作者：
Rissanen, K.
中科院分区：
文献类型：
--
作者：
Giese, M.;Albrecht, M.;Rissanen, K.
在过去的四分之一个世纪里，阴离子-π相互作用，直觉上的排斥力，从有争议的变成了公认的非共价相互作用。在这个时间范围内，问题“阴离子-π相互作用。它们存在吗？“的问题得到了解答，更重要的是，它的功能相关性得到了证明。这篇专题文章综述阴离子π在气相、溶液及固态下的研究结果，并重点介绍阴离子π相互作用在阴离子识别、传感、传输及催化方面的应用。此外，这种弱分子间力的生化相关性进行了全面审查。
Anion-pi interactions, intuitively repulsive forces, turned from controversial to a well-established non-covalent interaction over the past quarter of a century. Within this time frame the question "Anion-pi interactions. Do they exist?" could be answered and even more importantly its functional relevance was proven. The present feature article summarizes the experimental findings of anion-pi studies in the gas phase, solution and in the solid state and highlights the application of anion-pi interactions in anion recognition, sensing and transport as well as in catalysis. Moreover, the biochemical relevance of this weak intermolecular force is comprehensively reviewed.