Conformational Aspects of Many-Membered Rings†
Conformational Aspects of Many-Membered Rings†
复制标题
DOI：
10.1002/anie.196610001
复制
发表时间：
1966-12
影响因子：
--
通讯作者：
J. Dale
中科院分区：
文献类型：
--
作者：
J. Dale
首先回顾了构成环系结构单元的各种化学基团的立体化学。然后证明，即使是大环的无应变可能性也是有限的，并且理论推导的环构象通常与物理方法发现的构象相对应。从构象的角度解释了同系列化合物的物理性质和环化产率的变化。
The stereochemistry of the various chemical grouping which constitute the structural units of ring systems is first reviewed. It is then shown that the strain-free possibilities even of large rings are restricted, and that the ring conformation theoretically derived generally correspond to those found by physical methods. Variations of physical properties and of cyclization yield in homologous series are explained on a conformational basis.