Catalytic nanoarchitectonics for environmentally compatible energy generation
Catalytic nanoarchitectonics for environmentally compatible energy generation
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DOI：
10.1016/j.mattod.2015.08.021
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发表时间：
2016-01-01
期刊：
影响因子：
24.2
通讯作者：
Ariga, Katsuhiko
中科院分区：
文献类型：
--
作者：
Abe, Hideki;Liu, Jia;Ariga, Katsuhiko
环保能源管理是21世纪最大的挑战之一。将化学物质低温转化为电能，对于最大限度地减少对环境的影响，同时维持消耗性经济尤为重要。在这篇综述中，我们阐述了最通用的能量转换技术之一：多相催化剂。我们在材料科学的一个新兴范式：催化纳米建筑学的背景下，在不同尺度上建立了多相催化剂结构剪裁的完整性。首先介绍了能量转换催化的基本背景，并从催化尾气修复、燃料电池电催化和太阳能燃料的光合作用等几个方面对最新的能量转换催化技术进行了展望。最后，展望了催化纳米体系结构的未来发展：多相催化剂、有机分子甚至酶的可能组合，以实现反应选择性、高效和长寿命的能量转换技术，以迎接我们面临的挑战。
Environmentally compatible energy management is one of the biggest challenges of the 21st century. Lowtemperature conversion of chemical to electrical energy is of particular importance to minimize the impact to the environment while sustaining the consumptive economy. In this review, we shed light on one of the most versatile energy-conversion technologies: heterogeneous catalysts. We establish the integrity of structural tailoring in heterogeneous catalysts at different scales in the context of an emerging paradigm in materials science: catalytic nanoarchitectonics. Fundamental backgrounds of energy-conversion catalysis are first provided together with a perspective through state-of-the-art energy-conversion catalysis including catalytic exhaust remediation, fuel-cell electrocatalysis and photosynthesis of solar fuels. Finally, the future evolution of catalytic nanoarchitectonics is overviewed: possible combinations of heterogeneous catalysts, organic molecules and even enzymes to realize reaction-selective, highly efficient and long-life energy conversion technologies which will meet the challenge we face.