Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates.
Controlled photochemical release of nitric oxide from O(2)-naphthylmethyl- and O(2)-naphthylallyl-substituted diazeniumdiolates.
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DOI：
10.1021/ja027957h
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发表时间：
2002-10
影响因子：
15
通讯作者：
K. Bushan;Hua Xu;P. Ruane;R. D’Sa;Christopher M. Pavlos;Joseph A. Smith;Tevye C. Celius;J. Toscano
中科院分区：
文献类型：
--
作者：
K. Bushan;Hua Xu;P. Ruane;R. D’Sa;Christopher M. Pavlos;Joseph A. Smith;Tevye C. Celius;J. Toscano
The photochemistry of O2-naphthylmethyl- and O2-naphthylallyl-substituted diazeniumdiolates has been investigated. Electron-donating methoxy group substitution is shown to have a significant effect on the observed photochemistry, with the appropriate substitution pattern resulting in efficient diazeniumdiolate photorelease. Observed nitric oxide release rates from these photoprecursors are consistent with those expected for normal thermal dissociation of the diazeniumdiolate in aqueous solutions and show the same pH dependence.
