Catalysis by polyoxometalates
Catalysis by polyoxometalates
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发表时间：
2002
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影响因子：
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通讯作者：
I. Kozhevnikov
中科院分区：
文献类型：
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作者：
I. Kozhevnikov
Series Preface. Preface to Volume 2. 1. Introduction. 1.1 Scope and definitions. 1.2 Nomenclature. 1.3 Historical background. 1.4 Introduction to catalysis by polyoxometalates. References. 2. Properties of Polyoxometalates. 2.1 Structures of polyoxometalates. 2.2 Crystal structure of heteropoly compounds. 2.3 Thermal stability. 2.4 Solubility. 2.5 Formation and state in solution. 2.6 Acid properties. 2.7 Redox properties. References. 3. Synthesis of Polyoxometalates. 3.1 General methods of synthesis. 3.2 Keggin polyoxometalates. 3.3 Wells-Dawson polyoxometalates. 3.4 Sandwich-type polyoxometalates. 3.5 Peroxo polyoxometalates. 3.6 Polyoxometalate catalysts. References. 4. Acid Catalysis by Heteropoly Compounds. 4.1 General overview. 4.2 Homogeneous acid catalysis. 4.3 Acid-catalysed reactions in biphasic liquid-liquid systems. 4.4 Heterogeneous acid catalysts. 4.5 Deactivation and regeneration of solid heteropoly acid catalysts. References. 5. Polyoxometalates as Catalysts for Selective Oxidation. 5.1 Liquid-phase oxidation. 5.2 Gas-phase oxidation. References. 6. Miscellaneous Catalytic Applications of Polyoxometalates. 6.1 Hydrogenation, carbonylation and related reactions. 6.2 Polyanion-stabilised clusters. 6.3 Polyoxometalates as catalyst precursors. References. 7. Catalysis by Polyoxometalates in Industry. 7.1 Acid catalysis. 7.2 Selective oxidation. References. 8. Other Applications of Polyoxometalates. 8.1 Analytical chemistry. 8.2 Separation. 8.3 Corrosion-resistant coatings. 8.4 Polyoxometalates as additives to inorganic and organic matrices. 8.5 Membranes. 8.6 Polyoxometalates in medicine: antiviral and antitumoral activity. References. Index.
