Production of a polymer with highly anisotropic conductivity and structure by Co-electroprecipitation of an imide anion radical and polycation
Production of a polymer with highly anisotropic conductivity and structure by Co-electroprecipitation of an imide anion radical and polycation
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DOI：
10.1021/ja00067a013
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发表时间：
1993-07
影响因子：
15
通讯作者：
L. Miller;C. Zhong;P. H. Kasai
中科院分区：
文献类型：
--
作者：
L. Miller;C. Zhong;P. H. Kasai
在固体电极或汞表面上，由含有N，N-双（对磺酸基苯基）萘二甲酰亚胺二钠（1）和阳离子聚合物聚（二烯丙基二甲基铵）（2 +）的水溶液通过电还原生长聚合物膜。膜形成的电化学研究报告。将膜（50-300 μm厚）从电极上去除，并通过XPS、ESR、UV、维斯、NIR和IR光谱进行表征。该膜在干燥空气中稳定数月。它们以π-二聚体和π-叠层的形式含有2 +和阴离子自由基（1 -
Polymer films were grown by electroreduction on solid electrodes or a mercury surface from an aqueous solution containing disodium N,N-bis(p-sulfonatophenyl)naphthalenedicarboximide (1) and the cationic polymer poly(diallyldimethylammonium) (2 + ). Electrochemical studies of the film formation are reported. The films (50-300 μm thick) were removed from the electrode and characterized by XPS, ESR, UV, VIS, NIR, and IR spectroscopy. The films were stable in dry air for months. They contain 2 + and anion radicals (1 - ) in the form of π-dimers and π-stacks