PREPARATION AND REACTIVITY OF 16-ELECTRON HALF-SANDWICH RUTHENIUM COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF (ETA-5-C5ME5)RU(PPRI3)CL
PREPARATION AND REACTIVITY OF 16-ELECTRON HALF-SANDWICH RUTHENIUM COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF (ETA-5-C5ME5)RU(PPRI3)CL
复制标题
DOI：
10.1039/c39880000278
复制
发表时间：
1988-02-15
影响因子：
--
通讯作者：
TILLEY, TD
中科院分区：
文献类型：
--
作者：
CAMPION, BK;HEYN, RH;TILLEY, TD
新型16电子钌化合物(η5-C5Me5)Ru(L)Cl [(1), L = PPri3; (2)、分别由[(η5-C5Me5)RuCl]4和PPri3或PCy3制备L=PCy3](Cy=环己基)，并确定了(1)的X射线晶体结构；描述了标题化合物与CO、C2H4、吡啶和PhSiH3的反应。
The new 16-electron ruthenium compounds (η5-C5Me5)Ru(L)Cl [(1), L = PPri3; (2), L = PCy3](Cy = cyclohexyl) were prepared from [(η5-C5Me5)RuCl]4 and PPri3 or PCy3, respectively, and the X-ray crystal structure of (1) has been determined; reactions of the title compounds with CO, C2H4, pyridine, and PhSiH3 are described.