Heterogeneous Hydroxyl-Directed Hydrogenation: Control of Diastereoselectivity through Bimetallic Surface Composition
Heterogeneous Hydroxyl-Directed Hydrogenation: Control of Diastereoselectivity through Bimetallic Surface Composition
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DOI：
10.1021/acscatal.1c01434
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发表时间：
2021-05
期刊：
影响因子：
12.9
通讯作者：
Alexander J. Shumski;W. A. Swann;Nicole J. Escorcia;Christina W. Li
中科院分区：
文献类型：
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作者：
Alexander J. Shumski;W. A. Swann;Nicole J. Escorcia;Christina W. Li
在定向氢化反应中，产物的选择性由底物上的辅助导向基团与催化剂的结合决定，通常由均相的Rh和Ir催化。
Directed hydrogenation, in which product selectivity is dictated by the binding of an ancillary directing group on the substrate to the catalyst, is typically catalyzed by homogeneous Rh and Ir com...