Hydrogen generating gel systems induced by visible light
Hydrogen generating gel systems induced by visible light
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DOI：
10.1039/b908144e
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发表时间：
2009-01-01
期刊：
影响因子：
3.4
通讯作者：
Yoshida, Ryo
中科院分区：
文献类型：
--
作者：
Okeyoshi, Kosuke;Yoshida, Ryo
作者试图通过使用凝胶在可见光和水提供时产生氢气来实现人工光合作用系统。设计了三种类型的凝胶，包括带有敏化剂、电子受体和催化剂的电子传输电路。官能团通过聚合物网络紧密排列，以减少凝胶中的水分。在凝胶体系中，氢气的生成比在溶液体系中更有效，构建在凝胶网络中的所有官能团都有效地工作并相互协作产生氢气。
The authors tried to achieve artificial photosynthesis systems by using gels to generate hydrogen when visible light and water are supplied. Three types of gels involving an electronic transmission circuit with a sensitizer, an electron acceptor and a catalyst were designed. The functional groups were arranged closely by a polymer network to reduce water inside the gel. In the gel system, hydrogen was generated more efficiently than in the solution system, and all the functional groups constructed in the gel network worked effectively and cooperated each other to generate hydrogen.