Synthesis and degradation of branched, photo-labile poly(acrylic acid) and polystyrene
Synthesis and degradation of branched, photo-labile poly(acrylic acid) and polystyrene
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DOI：
10.1039/c8py01597j
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发表时间：
2019-01
影响因子：
4.6
通讯作者：
O. Eckardt;S. Seupel;G. Festag;M. Gottschaldt;F. Schacher
中科院分区：
文献类型：
--
作者：
O. Eckardt;S. Seupel;G. Festag;M. Gottschaldt;F. Schacher
本文采用自由基聚合法，在一种新合成的不对称邻硝基苄基交联剂和不同量的十二烷基硫醇（DDT）作为链转移剂的存在下，合成了支化光响应性聚（丙烯酸）和聚苯乙烯，并对其进行了表征和光解降解。
We present the synthesis, characterization and photolytical degradation of branched photo-responsive poly(acrylic acid) and polystyrene using free radical polymerization of acrylic acid/styrene in the presence of a newly synthesized asymmetric o-nitrobenzyl-based crosslinker and different amounts of dodecanethiol (DDT) as a chain transfer agent.