Simple Analysis of Atmospheric NO2, SO2, and O3 in Mountains by Using Passive Samplers
Simple Analysis of Atmospheric NO2, SO2, and O3 in Mountains by Using Passive Samplers
复制标题
使用被动采样器简单分析山区大气中的 NO2、SO2 和 O3
DOI：
10.1021/es981163e
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发表时间：
1999
影响因子：
11.4
通讯作者：
Y. Fuse
中科院分区：
文献类型：
--
作者：
E. Yamada;M. Kimura;K. Tomozawa;Y. Fuse
采用被动采样器对山区大气NO2、SO2和O3进行了简单分析，并将其应用于山区大气污染物的空间分析。比瑛在京都市。被动采样器暴露30天。使用柳泽型采样器进行NO2测定。通过Saltzman方法，以亚硝酸根离子的形式通过电化学计量法测量吸收的NO2。另一方面，制备了包括含有碳酸钠溶液的吸收剂过滤器的SO2采样器。用H_2O_2溶液将吸附的SO_2氧化为SO_4 ~（2-），用离子色谱法测定。对于O3测定，使用Ogawa臭氧采样器。O3与亚硝酸根离子反应生成硝酸根离子，用离子色谱法测定。NO2、SO2和O3样品的相对标准偏差分别为1.4%、3 - 10%和2 - 5%。在Mt.的13个地点设置了取样器。比永NO2浓度及其沿着坡分布的研究表明，比瑛每天和季节性变化都很大。这个季节...
A simple analysis of atmospheric NO2, SO2, and O3 in mountains by passive samplers was investigated and applied to the spatial analysis of air pollutants at Mt. Hiei in Kyoto City. Passive samplers were exposed for 30 days. Yanagisawa-type samplers were used for NO2 determination. The absorbed NO2 was measured as nitrite ion spectrophotometrically by the Saltzman method. On the other hand, SO2 samplers comprising an absorbent filter containing sodium carbonate solution were made. The absorbed SO2 was oxidized to SO42- with an H2O2 solution and determined by ion chromatography. For O3 determination, Ogawa ozone samplers were used. The O3 reacted with nitrite ion to produce nitrate ion, which was measured by ion chromatography. The relative standard deviations for NO2, SO2, and O3 samplers were 1.4%, 3−10%, and 2−5%, respectively. Samplers were set up in 13 locations at Mt. Hiei. The NO2 concentration and its distribution along the slope of Mt. Hiei changed considerably both daily and seasonally. The season...