Optical response of concentrated colloids of coinage metals in the near‐ultraviolet, visible, and infrared regions

Optical response of concentrated colloids of coinage metals in the near‐ultraviolet, visible, and infrared regions
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造币金属浓缩胶体在近紫外、可见光和红外区域的光学响应

DOI:
10.1063/1.462888
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发表时间:
1992
影响因子:
4.4
通讯作者:
S. Efrima
S. Efrima
中科院分区:
化学2区
文献类型:
--
作者:
I. Farbman;O. Levi;S. Efrima

文献摘要

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The optical response of two‐phase composite materials (cermet topography with coinage metals) at high filling factors under a wide range of particles sizes, frequencies, and experimental conditions is calculated using a model that combines multipolar interactions and particle size effects. The validity of the model is established for a real system of a silver colloid and the simulations are discussed in terms of the microscopic structural parameters and the interaction between the particles. The limitations of the Maxwell–Garnett model are explored and the transition between a dense system which primarily reflects light and a dilute composite which mostly transmits light is followed with the same model.