Conversion of carbohydrate biomass to γ-valerolactone by using water-soluble and reusable iridium complexes in acidic aqueous media.
Conversion of carbohydrate biomass to γ-valerolactone by using water-soluble and reusable iridium complexes in acidic aqueous media.
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DOI：
10.1002/cssc.201300245
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发表时间：
2013-07
期刊：
影响因子：
8.4
通讯作者：
Jin Deng;Yan Wang;T. Pan;Qingli Xu;Q. Guo;Yao Fu
中科院分区：
文献类型：
--
作者：
Jin Deng;Yan Wang;T. Pan;Qingli Xu;Q. Guo;Yao Fu
温和的操作：开发了一种在酸性水介质中将碳水化合物生物质转化为γ-戊内酯的催化方法。水溶性铱配合物具有极强的催化活性，可以高产、高吨地合成γ-戊内酯。均相催化剂也可以通过简单的相分离工艺回收再利用。
Mild-mannered manipulation: A catalytic method for the conversion of carbohydrate biomass to γ-valerolactone in acidic aqueous media has been developed. The water-soluble iridium complexes were observed to be extremely catalytically active for providing γ-valerolactone in high yields with high TONs. The homogeneous catalysts can also be recycled and reused by applying a simple phase separation process.