Exploiting donor-acceptor interactions in aqueous dynamic combinatorial libraries: exploratory studies of simple systems
Exploiting donor-acceptor interactions in aqueous dynamic combinatorial libraries: exploratory studies of simple systems
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DOI：
10.1039/c0sc00307g
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发表时间：
2010-11-01
期刊：
影响因子：
8.4
通讯作者：
Sanders, Jeremy K. M.
中科院分区：
文献类型：
--
作者：
Au-Yeung, Ho Yu;Cougnon, Fabien B. L.;Sanders, Jeremy K. M.
描述了基于二氧萘二胺（DN）的富电子供体构建块或基于萘二酰亚胺（NDI）的缺电子受体构建块的水性动态组合文库（dcl）的行为。详细探讨了浓度和离子强度对库分布和多样性的影响，以及对电子互补模板的响应，建立了在更复杂的库中使用的原则，从而产生了新一代的链链烷。
The behaviour of aqueous dynamic combinatorial libraries (DCLs) containing either electron-rich donor building blocks based on dioxynaphthalene (DN), or electron-deficient acceptor building blocks based on naphthalenediimide (NDI) are described. The influence of concentration and ionic strength on library distribution and diversity, together with the responses to electronically-complementary templates have been explored in detail, establishing the principles to be employed in more complex libraries leading to a new generation of catenanes.