Photosensitized conversion of 9,10-deoxytridachione to photodeoxytridachione.
Photosensitized conversion of 9,10-deoxytridachione to photodeoxytridachione.
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DOI：
10.1021/ol051887c
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发表时间：
2005-10
期刊：
影响因子：
5.2
通讯作者：
Daniel R. Zuidema;Aubry K. Miller;D. Trauner;Paul B. Jones
中科院分区：
文献类型：
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作者：
Daniel R. Zuidema;Aubry K. Miller;D. Trauner;Paul B. Jones
[reaction: see text] The photochemical conversion of 9,10-deoxytridachione to photodeoxytridachione has been photosensitized. The conversion was also quenched by piperylene. Photodeoxytridachione was produced in good yields under conditions in which only the cyclohexadiene group is sensitized. The results show that some, and perhaps all, of the photoreactions of 9,10-deoxytridachione occur through a triplet excited state. The mechanistic and biosynthetic implications of these results are discussed.
