Trifluoromethylation recations through trifluoromethyl radical
Trifluoromethylation recations through trifluoromethyl radical
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DOI：
10.1360/032012-266
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发表时间：
2012-09
影响因子：
10.4
通讯作者：
Xi Wang;Yan Zhang;J. Wang
中科院分区：
文献类型：
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作者：
Xi Wang;Yan Zhang;J. Wang
含三氟甲基基团的有机分子在功能材料、农药、医药等领域有着广泛的应用，因此，开发新的三氟甲基化方法已成为近年来的研究热点。在这种情况下，通过三氟甲基自由基形成碳-碳键是一种重要的策略。本文根据三氟甲基自由基形成碳-碳键的不同途径，综述了近年来三氟甲基自由基形成碳-碳键的研究进展。
Organic molecules that contain trifluoromethyl group have found wide applications in diverse areas such as functional materials, agrochemicals, pharmaceuticals and so on. Consequently, the development of novel methods of trifluoromethylation has become a hot topic in recent years. In this context, carbon-carbon bond formation through trifluoromethyl radical is an important strategy. In this review, the recent development of carbon-carbon bond formation through trifluoromethyl radical has been discussed according to the different approach toward trifluoromethyl radicals.