Amphiphilic silver particles for conductive inks with controlled wetting behavior
Amphiphilic silver particles for conductive inks with controlled wetting behavior
复制标题
DOI：
10.1016/j.matchemphys.2014.08.035
复制
发表时间：
2014-12-15
影响因子：
4.6
通讯作者：
Lewis, Jennifer A.
中科院分区：
文献类型：
--
作者：
Ahn, Bok Yeop;Lewis, Jennifer A.
银油墨在印刷电子产品中作为导电电极得到应用。两亲性银微粒是通过酰胺化反应用功能胺对 PAA 封端的颗粒进行改性而制备的。这些改性银颗粒可以分散在各种溶剂中，从水（ε = 80.4）到亲脂醇（ε = 3-17），以产生具有可调润湿性的导电油墨。使用这些墨水，我们展示了在 Kapton 上气溶胶喷射导电银图案（36 μm 宽，1.2 μm 厚）。在225℃热退火5分钟后获得3.7μΩ·cm的电阻率。在 1.4 KV 下进行短至 1 ms 的光子退火后，可实现类似的电阻率 (3.9 mu Omega cm)。 (C) 2014 Elsevier B.V. 保留所有权利。
Silver inks find applications in printed electronics as conductive electrodes. Amphiphilic silver microparticles are prepared by modifying PAA-capped particles with functional amines via an amidation reaction. These modified silver particles can be dispersed in a wide variety of solvents ranging from water (epsilon = 80.4) to lipophilic alcohols (epsilon = 3-17) to yield conductive inks with tunable wettability. Using these inks, we have demonstrated aerosol jet printing of conductive silver patterns (36 mu m wide, 1.2 mu m thick) on Kapton. Electrical resistivity of 3.7 mu Omega cm is obtained after thermal annealing at 225 degrees C for 5 min. Similar electrical resistivity (3.9 mu Omega cm) is achieved after photonic annealing as short as 1 ms at 1.4 KV. (C) 2014 Elsevier B.V. All rights reserved.