Anion-induced adsorption of thallium complex on silver electrodes.

Anion-induced adsorption of thallium complex on silver electrodes.
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DOI:
10.1016/j.jcis.2004.08.114
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发表时间:
2005-02
影响因子:
9.9
通讯作者:
T. Girija;M. Sangaranarayanan
T. Girija;M. Sangaranarayanan
中科院分区:
化学1区
文献类型:
--
作者:
T. Girija;M. Sangaranarayanan

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使用循环伏安法、计时库仑法和阻抗研究来分析铊离子在多晶银电极上的界面行为。指出了与导致铊络合物阴离子诱导吸附的溴离子相关的特异性,并推导了铊络合物的化学计量。
The interfacial behavior of thallium ions on polycrystalline silver electrodes is analyzed using cyclic voltammetric and chronocoulometric and impedance studies. The specificity associated with bromide ions leading to the anion-induced adsorption of the thallium complex is pointed out and the stoichiometry of the thallium complex is deduced.