Environment-sensitive fluorophore emitting in protic environments.

Environment-sensitive fluorophore emitting in protic environments.
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DOI:
10.1021/ol062490r
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发表时间:
2006-11
期刊:
影响因子:
5.2
通讯作者:
S. Uchiyama;Kazuyuki Takehira;Toshitada Yoshihara;S. Tobita;T. Ohwada
S. Uchiyama;Kazuyuki Takehira;Toshitada Yoshihara;S. Tobita;T. Ohwada
中科院分区:
化学1区
文献类型:
--
作者:
S. Uchiyama;Kazuyuki Takehira;Toshitada Yoshihara;S. Tobita;T. Ohwada

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本文报道了8-甲氧基-4-甲基-2H-苯并[g]色烯-2-酮(1)的荧光性质。荧光团1在非质子溶剂(例如,荧光量子产率Phi(f)450 nm)在质子溶剂(例如,Phi(f)= 0.21,在甲醇中)。荧光团1在开发新的荧光(荧光“关-开”)传感器中也显示出良好的适用性。[结构:见正文]
The unusual fluorescence properties of 8-methoxy-4-methyl-2H-benzo[g]chromen-2-one (1) are described. The fluorophore 1 is almost nonfluorescent in aprotic solvent (e.g., fluorescence quantum yield Phi(f) 450 nm) in protic solvent (e.g., Phi(f) = 0.21 in methanol). The fluorophore 1 also shows good applicability in developing a new fluorogenic (fluorescent "off-on") sensor. [structure: see text]