THE RATE OF THE REACTION OF OH WITH HCL
THE RATE OF THE REACTION OF OH WITH HCL
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DOI：
10.1002/kin.550160910
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发表时间：
1984-01-01
影响因子：
1.5
通讯作者：
SMITH, CA
中科院分区：
文献类型：
--
作者：
MOLINA, MJ;MOLINA, LT;SMITH, CA
The absolute rate constant for the OH + HCl reaction has been measured from 240 to 295 K utilizing the techniques of laser/flash photolysis‐resonance fluorescence. The HCl concentrations were monitored continuously by ultraviloet and infrared spectrophotometry. The results can be fit to the following Arrhenius expression: \documentclass{article}\pagestyle{empty}\begin{document}$$k_1 = (4.6{\rm } \pm {\rm }0.3){\rm } \times {\rm }10^{ - 12} \exp [- (500{\rm } \pm {\rm }60)/T{\rm cm}^3 /{\rm molecule} \cdot {\rm s}$$\end{document} The rate constant values obtained in this study are 20–30% larger than those recommended previously for modeling of stratospheric chemistry.
The absolute rate constant for the OH + HCl reaction has been measured from 240 to 295 K utilizing the techniques of laser/flash photolysis‐resonance fluorescence. The HCl concentrations were monitored continuously by ultraviloet and infrared spectrophotometry. The results can be fit to the following Arrhenius expression: \documentclass{article}\pagestyle{empty}\begin{document}$$k_1 = (4.6{\rm } \pm {\rm }0.3){\rm } \times {\rm }10^{ - 12} \exp [- (500{\rm } \pm {\rm }60)/T{\rm cm}^3 /{\rm molecule} \cdot {\rm s}$$\end{document} The rate constant values obtained in this study are 20–30% larger than those recommended previously for modeling of stratospheric chemistry.