A novel oxide composite reinforced with a ductile phase for very high temperature structural materials

A novel oxide composite reinforced with a ductile phase for very high temperature structural materials
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一种用于超高温结构材料的韧性相增强的新型氧化物复合材料

DOI:
10.1007/s100190100131
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发表时间:
2001
期刊:
影响因子:
--
通讯作者:
K. Shimizu
K. Shimizu
中科院分区:
--
文献类型:
--
作者:
Y. Waku;S. Sakata;A. Mitani;K. Shimizu

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随着温度的升高,几乎所有金属和陶瓷多晶材料的强度都会迅速下降。本文采用Al_2O_3-Y_3Al_5O_(12)(Y_3Al_5O_(12))-ZrO_2三元共晶混合物定向凝固的方法,制备了一种在1873K下具有不同显微组织的韧性相增强的强韧氧化物复合材料。该复合材料具有由单晶Al_2O_3、单晶Y_2O_3和单晶c-ZrO_2组成的无晶界互穿网络的微观结构。在这些相之间的界面上没有观察到非晶相,并形成了相对相容的界面。这种材料在1873K时表现出塑性变形,表明具有高屈服弯曲强度。该复合材料在1873K时的平均弯曲强度约为850 Mpa,约为相同成分烧结复合材料的57倍,1873K时的延性断裂至今未见报道。因此,在机械工程中可以考虑几个有用的应用。
The strength of nearly all metallic and ceramic polycrystalline materials drops off rapidly with increases in temperature. Here we have developed a strong and tough oxide composite reinforced with a ductile phase at 1873 K with a different kind of microstructure, made by unidirectional solidification of an Al2O3-Y3Al5O12(YAG)-ZrO2ternary eutectic mixture. This composite has a microstructure in which continuous networks of single-crystal Al2O3, single-crystal YAG and single-crystal c-ZrO2interpenetrate without grain boundaries. No amorphous phases are observed at the interfaces between these phases and relatively compatible interfaces are formed. This material displays plastic deformation at 1873 K indicating high yielding flexural strength. This composite's average flexural strength at 1873 K of around 850 MPa—approximately 57 times higher than that of the sintered composite with the same composition, and its ductile fracture at 1873 K have never been found up to now. Consequently several useful applications can be considered in mechanical engineering.
DOI: 10.1007/978-1-4613-2233-7
发表时间: 1986-12
期刊: --
影响因子: --
作者:
R. E. Tressler;G. Messing;C. Pantano;R. Newnham
通讯作者: R. E. Tressler;G. Messing;C. Pantano;R. Newnham