Acid-Base Equilibria in Benzene. I. A Colligative Property and Infrared Study of the Reactions of Some Carboxylic Acids and Nitrogen Bases
Acid-Base Equilibria in Benzene. I. A Colligative Property and Infrared Study of the Reactions of Some Carboxylic Acids and Nitrogen Bases
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苯中的酸碱平衡。
DOI：
10.1021/ja01082a004
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发表时间：
1965
期刊：
影响因子：
--
通讯作者：
Atsuoshi Saito
中科院分区：
文献类型：
--
作者：
S. Bruckenstein;Atsuoshi Saito
对苯进行的定量平衡研究相对较少。 LaMer 和 Downes 1 的早期指示剂研究涉及指示剂酸和碱以及无色酸和碱，表明水平衡概念无法充分解释他们的实验结果。他们通过假设平衡常数的形式来半定量地解释他们的数据
Relatively few quantitative equilibrium studies have been made in benzene. Early indicator studies by LaMer and Downes, 1 involving both indicator acids and bases with colorless acids and bases, demonstrated that aqueous equilibrium concepts could not ade-quately account for their experimental results. They interpreted their data semiquantitatively by assuming equilibrium constants of the form