Gold-catalyzed efficient formation of alkenyl enol esters/carbonates from trimethylsilylmethyl-substituted propargyl esters/carbonates.

Gold-catalyzed efficient formation of alkenyl enol esters/carbonates from trimethylsilylmethyl-substituted propargyl esters/carbonates.
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DOI:
10.1002/chin.200704056
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发表时间:
2006-09
期刊:
影响因子:
5.2
通讯作者:
Shaozhong Wang;Liming Zhang
Shaozhong Wang;Liming Zhang
中科院分区:
化学1区
文献类型:
--
作者:
Shaozhong Wang;Liming Zhang

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研究了一种金催化合成烯基烯醇酯/碳酸酯的新方法。除了反应条件温和、催化效率高外,壬烯醇双键的E-选择性也很好。
A gold-catalyzed efficient method for the preparation of alkenyl enol esters/carbonates is developed. Besides the mild reaction conditions and high catalytic efficiency, the excellent E-selectivity of the nonenolic double bond is remarkable.