Asymmetric reactions on chiral catalysts entrapped within a mesoporous cage.
Asymmetric reactions on chiral catalysts entrapped within a mesoporous cage.
复制标题
DOI：
10.1039/b614635j
复制
发表时间：
2007-02
影响因子：
4.9
通讯作者：
Hengquan Yang;Jun Li;Jie Yang;Zhimin Liu;Qihua Yang;Can Li
中科院分区：
文献类型：
--
作者：
Hengquan Yang;Jun Li;Jie Yang;Zhimin Liu;Qihua Yang;Can Li
证实了Co（Salen）和Ru-TsDPEN等均相手性催化剂在SBA-16介孔笼中的包封性；包封催化剂的性能与均相催化剂相当，可循环使用10次以上，且催化性能没有明显损失。
The encapsulation of homogeneous chiral catalysts, e.g. Co(Salen) and Ru-TsDPEN, in the mesoporous cage of SBA-16 is demonstrated; the encapsulated catalysts show performance as good as that of the homogeneous catalysts, and can be recycled for more than 10 times without significant loss of catalytic performance.