Crystal structure and orientation of organic semiconductor thin films by microcrystal electron diffraction and grazing-incidence wide-angle X-ray scattering

Crystal structure and orientation of organic semiconductor thin films by microcrystal electron diffraction and grazing-incidence wide-angle X-ray scattering
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DOI:
10.1039/d0cc00119h
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发表时间:
2020-04-18
影响因子:
4.9
通讯作者:
Nannenga, Brent L.
Nannenga, Brent L.
中科院分区:
化学2区
文献类型:
--
作者:
Levine, Andrew M.;Bu, Guanhong;Nannenga, Brent L.

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我们使用微晶电子衍射(MicroED),以确定三个有机半导体的结构,并表明这些结构可以使用沿着与掠入射广角X射线散射(GIWAXS),以了解薄膜中的晶体包装和取向。这些互补技术一起为有机半导体薄膜提供了独特的结构见解,这类材料的器件特性和电子行为敏感地依赖于固态秩序。
We use microcrystal electron diffraction (MicroED) to determine structures of three organic semiconductors, and show that these structures can be used along with grazing-incidence wide-angle X-ray scattering (GIWAXS) to understand crystal packing and orientation in thin films. Together these complimentary techniques provide unique structural insights into organic semiconductor thin films, a class of materials whose device properties and electronic behavior are sensitively dependent on solid-state order.