Towards an understanding of the mechanism of electron-capture dissociation: a historical perspective and modern ideas

Towards an understanding of the mechanism of electron-capture dissociation: a historical perspective and modern ideas
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DOI:
10.1255/ejms.517
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发表时间:
2002-01-01
影响因子:
1.3
通讯作者:
Jensen, F
Jensen, F
中科院分区:
化学4区
文献类型:
--
作者:
Zubarev, RA;Haselmann, KF;Jensen, F

文献摘要

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电子俘获解离(ECD)是一种利用离子-电子复合反应的新型裂解技术。后者在其他研究领域有相似之处;揭示这些相似之处有助于理解ECD机制。概述了ECD相关现象和ECD发现和发展的历史。目前对ECD机制的看法进行了讨论,使用已发表的和新的例子。
Electron-capture dissociation (ECD) is a new fragmentation technique that utilizes ion-electron recombination reactions. The latter have parallels in other research fields; revealing these parallels helps to understand the ECD mechanism. An overview is given of ECD-related phenomena and of the history of ECD discovery and development. Current views on the ECD mechanism are discussed using both published and new examples.