PRESSURE EFFECTS ON THE HYDROGEN-BOND IN ICE UP TO 80 GPA

PRESSURE EFFECTS ON THE HYDROGEN-BOND IN ICE UP TO 80 GPA
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DOI:
10.1016/0022-2860(94)87045-4
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发表时间:
1994-06-16
影响因子:
3.8
通讯作者:
PRUZAN, P
PRUZAN, P
中科院分区:
化学2区
文献类型:
--
作者:
PRUZAN, P

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冰中的氢键性质在压力下表现出显着的差异上得到的O-H的关联。O系统。使用我们的高压数据有关的对称伸缩频率nu(OH)和冰VII-VIII过渡线的变化,它表明,所谓的有序对称冰X可能是预期的氧-氧距离接近2.3比2.4埃。
The hydrogen bond properties in ice under pressure exhibit marked differences with the correlations obtained on O-H...O systems. Using our high-pressure data concerning the variation of the symmetric stretching frequency nu(OH) and the ice VII-VIII transition line, it is shown that the so-called ordered symmetric ice X may be expected for an oxygen-oxygen distance closer to 2.3 than 2.4 angstrom.