Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer
Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer
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DOI:
10.1039/d2cc00473a
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发表时间:
2022-03-10
影响因子:
4.9
通讯作者:
Mazzanti, Marinella
中科院分区:
文献类型:
--
作者:
Barluzzi, Luciano;Jori, Nadir;Mazzanti, Marinella
The reaction of a terminal Mo(II) nitride with a U(III) complex yields a heterodimetallic UMo nitride which is the first example of a transition metal-capped uranium nitride. The nitride is triply bonded to U(V) and singly bonded to Mo(0) and supports a UMo interaction. This compound shows reactivity toward CO oxidation.