A Stable Sensing-Electrode Material in Reducing Atmosphere at High Temperature for Zirconia-Based Amperometric NOx Sensor

A Stable Sensing-Electrode Material in Reducing Atmosphere at High Temperature for Zirconia-Based Amperometric NOx Sensor
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DOI:
10.5796/electrochemistry.81.74
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发表时间:
2013-02
期刊:
影响因子:
2.5
通讯作者:
T. Ueda;H. Okawa;Seiji Takahashi
T. Ueda;H. Okawa;Seiji Takahashi
中科院分区:
工程技术4区
文献类型:
--
作者:
T. Ueda;H. Okawa;Seiji Takahashi

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采用喷雾热解法合成了 La0.8Sr0.2Al1−xMnxO3 (x = 0, 0.2, 0.4, 0.6),作为氧化锆基电流型 NOx 传感器在高温还原气氛中稳定的传感电极(SE)材料。 La0.8Sr0.2AlO3氧化物在还原气氛中(4vol.% H2,750℃,2h)处理后的XRD衍射图与制备的相同。使用处理后的氧化物作为SE的传感器对500ppm NO 2 的响应为-1.3μA,该值大约等于使用处理前的氧化物获得的值。 © 日本电化学会,保留所有权利。
La0.8Sr0.2Al1−xMnxO3 (x = 0, 0.2, 0.4, 0.6) were synthesized using a spray pyrolysis method as a stable sensingelectrode (SE) material in high-temperature reducing atmosphere for zirconia-based amperometric NOx sensor. The XRD diffraction pattern of the La0.8Sr0.2AlO3 oxide after treatment in a reducing atmosphere (in 4vol.% H2 at 750°C for 2h) was same with the one as-prepared. A response to 500ppm NO2 of a sensor using the oxide after treatment as an SE was −1.3μA, a value approximately equal to that obtained using an oxide before treatment. © The Electrochemical Society of Japan, All rights reserved.