Strategy of interference-free atomic hydrogen detection in flames using femtosecond multi-photon laser-induced fluorescence

Strategy of interference-free atomic hydrogen detection in flames using femtosecond multi-photon laser-induced fluorescence
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飞秒多光子激光诱导荧光无干扰火焰中原子氢检测策略

DOI:
10.1016/j.ijhydene.2016.05.294
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发表时间:
2017-02
影响因子:
7.2
通讯作者:
Li Zhongshan
Li Zhongshan
中科院分区:
工程技术2区
文献类型:
--
作者:
Li Bo;Zhang Dayuan;Li Xiaofeng;Gao Qiang;Yao Mingfa;Li Zhongshan

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Hydrogen atoms are key species in combustion of hydrogen/hydrocarbon fuels. Interference-free detection of hydrogen atoms natively generated in flames using femtosecond laser-induced fluorescence (LIF) was investigated employing two colors, i.e., 243 nm and 486 nm, as excitation source: two-photon excitation followed by a relay one-photon excitation. This strategy was compared with another commonly adopted two-photon LIF strategy using 205 nm for excitation. The potential interferences were investigated, and a direct verification method was proposed to prove this strategy be interference-free, and imaging of hydrogen atoms natively generated in methane/air flames was achieved.
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